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Go to Editorial ManagerThe polyethylene terephthalate (PET) was prepared from PET flakes of empty local water drinking bottles and diagnosis by infrared spectroscopy (IR). The glass transition temperature, melting temperature T m and heat capacity were indicated by differential scanning calorimeter (DSC). Part hundred ratios (phr , s) of (PET) were added to study its effect on concrete properties. Additives of (phr) impart performance such as increased cement dispersion, enabling drastically reduced water requirements. Enhance the mortar cubes performance; depend on the compatibility of cement with PET. Porosity of mortar cubes with cement, sand and added PET products were calculated. Maximum and minimum Compressive strength were calculated 58.76 MPa, and 24.0 MPa at phr 0.04 and 0.07 of PET with cement. And PET with cement and sand were calculated 16.5 MPa and 4 MPa at dosages 0.03 gm. and 0.08 gm. The relative dosages in calculating porosity percentages are (0.06, 0.1 and 0.3) gm.
4-Stearoylresorcinol was prepared by acylation of resorcinol with stearoyl chloride in the presence of zinc chloride as catalyst in a batch reactor. The temperature range of reaction was (50-80)°C. The rate of acylation increased with temperature up to (70°C). The conversion of reactants appeared to follow second order kinetic model. The reaction rate constant was (0.0031 1/mol.min) and was higher at higher temperatures. Activation energy was (16.8258 kJ/mol). The optimal catalyst concentration was (2.9936 mol/l). Also, a quantitative relationship was derived to represent the weight of the product as a function to the reaction variables. The quantitative relationship gave mean deviation equal to (5%). The product concentration was measured by UV spectroscopy.
Polyethylene terephthalate (PET) was prepared from (PET) flakes and 25% of NaOH solution were added to in tri-neck flask, the reaction run for six hours at temperature (100-130) oC and the precipitate was reacted with ethylene glycol at temperature (130-160) oC. IR spectrophotometer was used for the diagnoses of (PET). Differential scanning calorimeter (DSC) is used to indicate glass transition temperature Tg, the melting temperature Tm and the heat absorbed. Part hundred ratios (phr,s) of (PET) rather than dosage of PET in gms. To concrete cubes were added to study its effect on concrete properties. Additives of (phr,s) impart performance such as increased cement dispersion, and enhance the performance of concrete which was appeared in maintaining a lengthening or slow the setting time that meets product and job needs. Maximum and minimum compressive strength is 43.7 MPa and 30.0 MPa at 0.3 gm. and 0.1 gm. respectively.
The enormous volume of crude oil that needs to be transported results from the growing demand for petroleum. One of the most practical ways to move crude oil is via pipelines. This paper's primary objective is to examine the effects of sulphur, one of the components of crude oil, on welded pipes (API 5L X60, X46, and X42 pipes as well as ASTM A106 pipes). It also aims to show how sulphur content influences different kinds of pipes separately from the other important components of crude oil. The sulphur content of crude oil is determined using the TR-TCXRF equipment. The corrosion rates of welded pipes in four immersion solutions (Different percentages of sulphur content) were computed using weight loss. The samples' corrosion characteristics were assessed morphologically using an optical microscope (OM), scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS). Petroleum welded pipelines' mechanical qualities and resistance to corrosion are significantly impacted by sulphur; an increase in sulphur concentration resulted in a higher rate of corrosion and a decrease in mechanical properties. Among all the welded pipes utilized in the paper, the API 5L X60 welded pipe had the highest corrosion rate, whereas X46 welded pipe was more corrosion-resistant than X46 and X42 in API 5L-type pipes and ASTM A106 pipe.