Cover
Vol. 25 No. 1 (2025)

Published: September 9, 2025

Pages: 47-55

Original Article

The Impact of Iraqi Crude Oil Sulphur Content on the Mechanical Characteristics and Corrosion Resistance of Various Carbon Steel Grades Pipeline Welded Joints

Abstract

The enormous volume of crude oil that needs to be transported results from the growing demand for petroleum. One of the most practical ways to move crude oil is via pipelines. This paper's primary objective is to examine the effects of sulphur, one of the components of crude oil, on welded pipes (API 5L X60, X46, and X42 pipes as well as ASTM A106 pipes). It also aims to show how sulphur content influences different kinds of pipes separately from the other important components of crude oil. The sulphur content of crude oil is determined using the TR-TCXRF equipment. The corrosion rates of welded pipes in four immersion solutions (Different percentages of sulphur content) were computed using weight loss. The samples' corrosion characteristics were assessed morphologically using an optical microscope (OM), scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS). Petroleum welded pipelines' mechanical qualities and resistance to corrosion are significantly impacted by sulphur; an increase in sulphur concentration resulted in a higher rate of corrosion and a decrease in mechanical properties. Among all the welded pipes utilized in the paper, the API 5L X60 welded pipe had the highest corrosion rate, whereas X46 welded pipe was more corrosion-resistant than X46 and X42 in API 5L-type pipes and ASTM A106 pipe.

References

  1. N. Narimani, B. Zarei, H. Pouraliakbar, and G. Khalaj, “Predictions of corrosion current density and potential by using chemical composition and corrosion cell characteristics in microalloyed pipeline steels,” Measurement, Vol. 62, pp. 97-107, 2015.
  2. M. A. Adegboye, W. K. Fung, and A. Karnik, “Recent advances in pipeline monitoring and oil leakage detection technologies: Principles and approaches,” Sensors, Vol. 19, Issue 11, 2019. https://doi.org/10.3390/s19112548
  3. T. N. Wordofa, and P. J. Ramulu, “Gas metal arc welding input parameters impacts on weld quality characteristics of steel materials a comprehensive exploration,” Manufacturing Technology, Vol. 23, Issue 3, pp. 366-379, 2023.
  4. P. Hargiyarto, K. Syauqi, S. Sugiyono, A. Ardian, S. Sianipar, and L. A. Nadjib, “Analysis of quality student practice results in shielded metal arc welding,” Journal of Physics: Conference Series, Vol. 1700, Issue 1, 2020.
  5. S. K. Sharma, S. Maheshwari, “A review on welding of high strength oil and gas pipeline steels,” Journal of Natural Gas Science and Engineering, Vol. 38, pp. 203-217, 2017.
  6. H. M. Lieth, R. Al-Sabur, R. J. Jassim, and A. Alsahlani, “Enhancement of corrosion resistance and mechanical properties of API 5L X60 steel by heat treatments in different environments,” Journal of Engineering Research, Vol. 9, Issue 4B, 2021. https://doi.org/10.36909/jer.14591
  7. Y. Liu, J. Zeng, S. Liu, and H. Long, “Physical properties variation of crude oil under natural laboratory and its geological implications: Dongying Sag, eastern China,” Frontiers in Earth Science, Vol. 11, 2023.
  8. S. M. Awadh, and H. S. Al-Mimar, “Statistical analysis of the relations between API, specific gravity and sulfur content in the universal crude oil,” International Journal of Science and Research, Vol. 4, Issue 5, pp. 1279-1284, 2015.
  9. ASTM International, Standard Test Method for Sulfur in Petroleum Products by Wavelength Dispersive X-ray Fluorescence Spectrometry, ASTM International, 2010.
  10. A. K. Alzarqani, and F. J. Alduhaidahawi, “A Study of Sulfur Content in Crude Oil, Gasoline and Kerosene in Some Iraqi Oil Fields and Refineries,” International Journal of Health Sciences, Vol. 6, Issue S4, pp. 10548-10557, 2022.
  11. F. O. Kolawole, S. K. Kolawole, J. O. Agunsoye, J. A. Adebisi, S. A. Bello, and S. B. Hassan, “Mitigation of Corrosion Problems in API 5L Steel Pipeline – A Review,” Journal of Materials and Environmental Sciences, Vol. 9, Issue 8, pp. 2397-2410, 2018.
  12. P. C. Okonkwo, M. H. Sliem, R. A. Shakoor, A. M. A. Mohamed, and A. M. Abdullah, “Effect of temperature on the corrosion behavior of API X120 pipeline steel in H 2 S environment,” Journal of Materials Engineering and Performance, Vol. 26, pp. 3775-3783, 2017.
  13. M. Meriem-Benziane, B. Bou-Saïd, and N. Boudouani, “The effect of crude oil in the pipeline corrosion by the naphthenic acid and the sulfur: A numerical approach,” Journal of Petroleum Science and Engineering, Vol. 158, pp. 672-679, 2017. https://doi.org/10.1016/j.petrol.2017.08.073
  14. ASTM A751-14. Standard Test Methods, Practices and Terminology for Chemical Analysis of Steel Products, 2014.
  15. I. S. Bott, F. Siciliano, G. Z. Batista, and J. M. Gray, “Line Pipe Steels,” In Handbook of Pipeline Engineering, Cham: Springer International Publishing, pp. 285-310, 2024.
  16. ASTM International, Standard specification for seamless carbon steel pipe for high-temperature service, ASTM A 106, ASTM International, 2019.
  17. ASTM, E. Standard guide for preparation of metallographic specimens. American Society for Testing and Materials, West Conshohocken, 2011.
  18. A. H. Hattab, S. Beebany, A. S. Kaki, “The effect of H 2 SO 4 concentration on corrosion of Kirkuk's oil and gas pipelines with studying corrosion reaction rates kinetically,” Chemical Methodologies, Vol. 7, Issue 4, pp. 257-267, 2023.
  19. ASTM Committee G-1 on Corrosion of Metals, Standard practice for preparing, cleaning, and evaluating corrosion test specimens, ASTM international, 2017.
  20. ASTM Standard, Standard practice for laboratory immersion corrosion testing of metals, American Society for Testing and Materials G31-72, 2004.
  21. ASTM E1508‐12a, Standard Guide for Quantitative Analysis by Energy‐Dispersive Spectroscopy, 2012.
  22. S. Yang, M. Zhao, J. Feng, J. Li, C. Liu, “Induced-pitting behaviors of MnS inclusions in steel,” High Temperature Materials and Processes, Vol. 37, Issue 9-10, pp. 1007-1016, 2018. https://doi.org/10.1515/htmp-2017-0155
  23. W. Shi, S. Yang, A. Dong, J. Li, “Understanding the corrosion mechanism of spring steel induced by MnS inclusions with different sizes,” The Journal of the Minerals (Jom), Vol. 70, pp. 2513-2522, 2018.
  24. M. Nnoka, T. A. Jack, J. Szpunar, “Effects of different microstructural parameters on the corrosion and cracking resistance of pipeline steels: A review,” Engineering Failure Analysis, Vol. 159, 2024.
  25. Z. Wang, Z. Zhou, W. Xu, L. Yang, B. Zhang, Y. Li, “Study on inner corrosion behavior of high strength product oil pipelines,” Engineering Failure Analysis, Vol. 115, 2020.
  26. ASTM Standard, Standard Test Methods for Vickers Hardness and Knoop Hardness of Metallic Materials, Designation: E92-16, 2016.
  27. H. M. Lieth, M. A. Jabbar, R. J. Jassim, R. Al-Sabur, “Optimize the corrosion behavior of AISI 204Cu stainless steel in different environments under previous cold working and welding,” Metallurgical Research and Technology, Vol. 120, Issue 4, 2023. https://doi.org/10.1051/metal/2023058