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Go to Editorial ManagerThe polyethylene terephthalate (PET) was prepared from PET flakes of empty local water drinking bottles and diagnosis by infrared spectroscopy (IR). The glass transition temperature, melting temperature T m and heat capacity were indicated by differential scanning calorimeter (DSC). Part hundred ratios (phr , s) of (PET) were added to study its effect on concrete properties. Additives of (phr) impart performance such as increased cement dispersion, enabling drastically reduced water requirements. Enhance the mortar cubes performance; depend on the compatibility of cement with PET. Porosity of mortar cubes with cement, sand and added PET products were calculated. Maximum and minimum Compressive strength were calculated 58.76 MPa, and 24.0 MPa at phr 0.04 and 0.07 of PET with cement. And PET with cement and sand were calculated 16.5 MPa and 4 MPa at dosages 0.03 gm. and 0.08 gm. The relative dosages in calculating porosity percentages are (0.06, 0.1 and 0.3) gm.
It is very crucial to minimize the environmental impact that induced from the development of industry, by applying strict policies and innovate eco-friendly industries. Indeed, construction manufacture considered as one of the most industries that affect the environment, especially concrete production and usage in structural buildings. For instance, traditional concrete, which is consists of a high amount of cement, is contributed to the emission of CO 2 . Therefore, researchers seeking to develop a new technology of concrete by replacement some amount of cement by materials which are considered to become more friendly to the environment. Nowadays, this new technology is known as Green Concrete. The importance of using green concrete is not only to decrease the emission amounts of CO 2 but also to replace cement by industrial waste. In this paper, a review has been presented to understand green concrete benefits and materials that may be used instead of cement and aggregate.
Chemical additives were used in this research to improve the properties of the road subgrade layer. Cement, lime, and ferric chloride were used. Laboratory tests such as unconfined compressive strength, consistency limits, and wheel truck test were conducted. The results showed that adding these chemicals to the soil increases the ability of the soil to work, its resistance, and its durability. The optimum percentage of chemical additives that is suitable for the addition to the soil of Al-Nasiriya city were 9 %, 10 %, and 2 % corresponding to cement, lime, and ferric chloride, respectively. According to the unconfined compressive strength test and with increase curing period, which gave good results in improving the strength of the soil. As for the consistency limits, all additives reduced the liquid limit and plasticity index and increased the plastic limit, according to the wheel track test, at 10,000 passes the Rutting depth was 32 mm for natural soil, also the depths were (14, 19, and 17 mm) with chemical additives, respectively.
The present work includes a study on the effect of loading rubber waste into cement mortar on the thermal and mechanical properties of a thermal insulator.The experimental work of the study included the preparation of ten models of 35 mm diameter and 5 mm thickness. Portland cement and natural sand were used as a matrix and rubber waste (extracted from the consumed tires) as a filler was added in weight percentages ( 5% ,10% ,15% ,20% ,25% ,30% ,35% ,40%,45% and 50%). Water was also used as a binder.Also, the experimental work included conducting a thermal conductivity test using Lee’s Disk method, and a hardness test using the Shore scale. The theoretical side included extraction of empirical equations, depending on the experimental results. The thermal conductivity equation was for two variables, temperature and mass fraction. While the hardness equation was for one variable, mass fraction. Theoretically determined heat capacity was extracted using the equations of the composites. Based on the empirical equations of thermal conductivity and hardness and using the technique of multi- objectives genetic algorithm, the optimum values of temperature and mass fraction were extracted, which achieve the best thermal insulation of the mortar. The results showed a significant decrease in thermal conductivity. The reduction in thermal conductivity was (90.3%) at 5% and reduced to (95.73%) at 50%. The specific heat capacity was increasing as the percentage of rubber waste increase. The results also indicated a decrease in hardness. The optimal value of thermal insulation was (0.02658 W/m 2 .ºC ) as a thermal conductivity and (58.07 N/m 2 ) as a hardness, at temperature (50°C) and mass fraction (27.764%) of rubber waste.
Polyethylene terephthalate (PET) was prepared from (PET) flakes and 25% of NaOH solution were added to in tri-neck flask, the reaction run for six hours at temperature (100-130) oC and the precipitate was reacted with ethylene glycol at temperature (130-160) oC. IR spectrophotometer was used for the diagnoses of (PET). Differential scanning calorimeter (DSC) is used to indicate glass transition temperature Tg, the melting temperature Tm and the heat absorbed. Part hundred ratios (phr,s) of (PET) rather than dosage of PET in gms. To concrete cubes were added to study its effect on concrete properties. Additives of (phr,s) impart performance such as increased cement dispersion, and enhance the performance of concrete which was appeared in maintaining a lengthening or slow the setting time that meets product and job needs. Maximum and minimum compressive strength is 43.7 MPa and 30.0 MPa at 0.3 gm. and 0.1 gm. respectively.
The effect of different dosages of the high range water reducing admixture–additive- (HRWRA), the commercially polymeric material (Plastocrete-N), on the corrosion resistance of embedded steel in concrete exposed to chloride solution in the absence and presence of sulfate ions was studied. In the present study, four levels of polymeric material (Plastocrete-N) (0.125%, 0.250%, 0.375%, and 0.500% by weight of cement) were used to prepare HRWRA treated concrete. The concrete specimens exposed to chloride and chloride–sulfate solutions at concentrations of (3.5% NaCl and 5% Na2SO4), at ambient temperature. The electrochemical behavior of steel in both reference and HRWRA concretes was studied under the effect of corrosive environments using corrosion measurement systems such as: a) half – cell potentials measurement system and b) accelerated corrosion test system. The results showed that a longer time of corrosion initiation (180 day) observed with 0.500% HRWRA containing concrete compared to other different HRWRA percentage including the reference concrete. It was concluded that the use of 0.500% HRWRA provided superior protection to steel reinforcement in concrete that subjected to corrosive environments. Furthermore, the steel with 0.500% HRWRA was subjected to corrosion test by mass loss, it is evident that a reduction in mass loss by about 90.2% and 85.2% in both solutions, respectively.
The problem of construction debris has been emerged as one of the most important environmental problems in the Iraqi governorates due to higher rates of population growth and the need for the establishment of new construction projects to rebuilding Iraq. Therefore, this research aims to estimate the quantity of construction debris in Basra governorate and suggested method for recycling the homogeneous to rubble material that can be used in the building after admixing with cement. The study estimated the quantity of this debris in Basra during the study period, amounting to a full year up to 177.907 tons, that is equivalent to an average of 0.06 tons/m². And recycling of debris concrete to give the results of the usual approach to the concrete and be within the limits allowed in the code of Iraq and the U.S. and can be used in the production of non-loading concrete blocks.