Cover
Vol. 14 No. 2 (2014)

Published: June 30, 2014

Pages: 67-76

Original Article

Evaluation of the Performance of Steel in Reinforced Concrete by Electrochemical Methods

Abstract

The effect of different dosages of the high range water reducing admixture–additive- (HRWRA), the commercially polymeric material (Plastocrete-N), on the corrosion resistance of embedded steel in concrete exposed to chloride solution in the absence and presence of sulfate ions was studied. In the present study, four levels of polymeric material (Plastocrete-N) (0.125%, 0.250%, 0.375%, and 0.500% by weight of cement) were used to prepare HRWRA treated concrete. The concrete specimens exposed to chloride and chloride–sulfate solutions at concentrations of (3.5% NaCl and 5% Na2SO4), at ambient temperature. The electrochemical behavior of steel in both reference and HRWRA concretes was studied under the effect of corrosive environments using corrosion measurement systems such as: a) half – cell potentials measurement system and b) accelerated corrosion test system. The results showed that a longer time of corrosion initiation (180 day) observed with 0.500% HRWRA containing concrete compared to other different HRWRA percentage including the reference concrete. It was concluded that the use of 0.500% HRWRA provided superior protection to steel reinforcement in concrete that subjected to corrosive environments. Furthermore, the steel with 0.500% HRWRA was subjected to corrosion test by mass loss, it is evident that a reduction in mass loss by about 90.2% and 85.2% in both solutions, respectively.

References

  1. ACI Committee 222, "Corrosion of Metals in Concrete", ACI 222R-96, Manual of Concrete Practice, (1996).
  2. Neville, A. M., "Properties of Concrete," Pearson Education Limited. 4th and final edition, (2000).
  3. Rasheeduzzafar, Dakhil, H.D., and AL-Gahtani, A.S., "Deterioration of Concrete Structures in the Environment of the Middle East", ACI Journal, Jan-Feb., (1984).
  4. Broomfield, J. P., "Corrosion of steel in concrete understanding, investigation and repair", E &FN SPON, (1997).
  5. Akroyd T. N. W., "Concrete properties and manufacture", OXFORED, LONDON, NEW YORK, PARIS, Library of Congress, (1962).
  6. Mays C., "Durability of concrete structures: investigation, repair, protection", 1st Ed., E & FN Spon, (1992).
  7. Mor A. and Mehta P.K., "Effect of superplasticizing admixtures on cement hydration", J. Cement and Concrete Research, Vol. 14, PP. 754-756, (1984).
  8. AL- Hubboubi S. K., "corrosion of steel reinforcement in high performance concrete containing local slag and corrosion inhibitor", M.Sc. Thesis, University of Technology, Jan., (2001).
  9. Dhir R., Tham K., Dransfield J., "Durability of concrete with a superplasticizing admixture", ACI SP–100, Vol.1, PP. 742-751, (1987).
  10. ASTM C 150-80, "Standard Specification for Portland cement", American Society for Testing and Materials, (1980).
  11. ASTM G1-03, "Standard practice for preparing, cleaning, and evaluating corrosion test specimens", American Society for Testing and Materials, (2003).
  12. British Standard Institute, B.S.1881: Part 108, "Method for making test cubes from fresh concrete", (1983).
  13. Standard Institute, B.S.1881: Part 110, "Method for making test cylinders from fresh concrete", (1983).
  14. ASTM C876-99, "Standard test method for half-cell potential of uncoated reinforced steel", (1999).
  15. Amleh L., "Bond deterioration of reinforcing steel in concrete due to corrosion", Ph. D. Thesis, McGill University, Canada, (2000).
  16. Ibrahim M., "Performance evaluation of concrete surface treatments in the Arabian Gulf", M. Sc. Thesis, King Fahd University of Petroleum and Minerals, Saudi Arabia, (1996).
  17. Klinc K., Uyan M. and Arioz O., "Effect of solfate on strength of Portland cement mortors", J. the Int. Soc. Of offshore and Polar Equations, Vol.24, (2005).
  18. Poursaee A., Laurent A. and Hasson C.M., "Corrosion of steel Bars in opc mortor exposed to chloride: macro and micro corrosion perspective", J. cement and concrete research, Vol. 40, PP. 426-430, (2010).
  19. Al-Amoudi O. S. B. and Maslehuddin M., "The effect of chloride and sulfate ions on reinforcement corrosion", J. Cement and Concrete Research, Vol. 23(1), PP. 139-46, (1993).
  20. Al-Amoudi O. S. B., Rasheeduzzafar, Maslehuddin M., Abduljauwad S. N., "Influence of sulfate ions on chloride induced reinforcement corrosion in Portland and blended cement concretes", Cement and Concrete Research, Vol. 16(1), PP. 3-11, (1994).
  21. Maslehuddin M., "The influence of Arabian Gulf environment on mechanisms of reinforcement corrosion", Ph.D. Thesis, Birmingham, UK: Aston University,1(994).
  22. Obserholster R. E., "Pore structure, permeability and diffusivity of hardened cement paste and concrete in relation to durability: Status and prospects", Proceedings of the 8th International Congress on the Chemistry of Cement, Rio de Janeiro, Brazil, Sub-Theme 4., PP. 323–35, (1986).
  23. Rio A., Turriziani R. I. l., "Cemento", Vol. 80(1), PP. 37–48, (1983).
  24. Stratful R. F., "Effect on reinforced concrete in sodium chloride and sodium sulfate environments", Mater Protect, Vol. 3(12), PP. 74–80, (1964).
  25. Bakker R. F. M, "Permeability of blended cement concretes", ACI Special Publication SP-79., American Concrete Institute, Detroit, p. 589–605, (1983).
  26. Al-Ta’ie S. A. A., "Durability of concrete incorporating corrosion inihibitor and air-entraning agent exposed to chloride-sulfate solution", M. Sc. Thesis, University of Technology, Iraq, (2005).
  27. Dehwah H. A., Maslehuddin M., Austin S. A., "Longterm effect of sulfate ions and associated cation type on chloride-induced reinforcement corrosion in Portland cement concretes", J. Cement and Concrete Composite, Vol. 24, PP. 17-25, (2002).