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Go to Editorial ManagerZinc and its alloy coatings are commonly used to provide cathodic protection for weathering steel. However, the steel substrate corrodes faster than the Zinc coating because of the coating's negative corrosion potential. Many studies have examined Zinc and alloy coatings' resistance to corrosion. Hot-dip galvanizing, Electrodeposition, and Zinc-rich coat (ZRC) spray are just some of the methods that can be used to deposit such coatings. Commercially available 99.95 % pure Zinc oxide was used in the electroplating process in this investigation. Steel samples were plated in Zinc sulphate and Zinc oxide solutions and were controlled by different bath parameters such as voltage, current, pH, temperature, and coating time. The addition of hexagonal Boron Nitride (h-BN) nanoparticles has also shown significant improvements in corrosion resistance. However, Zinc-based coating techniques reinforced with h-BN incorporation show the best corrosion current density ( I corr ) of Hot dip 2 % wt. (2.1 µA/cm 2 ), ZRC 2.5 % wt., (4.4 µA/cm 2 ), and electroplating 15.75 g/L (0.081 µA/cm 2 ), which is an order of magnitude lower than coatings without h-BNs. The corrosion rates and current densities of Zn/h-BN coated layers were investigated in a controlled laboratory environment that mimicked natural conditions (Rainwater solution) by extrapolating polarization curves.
This study presents both experimental and theoretical investigations of an absorption refrigeration system using environmentally friendly working fluids, specifically the acetone–zinc bromide (Acetone/ZnBr₂) pair. The system was designed to operate under outdoor climatic conditions in Hilla City, Iraq, utilizing hot water as the heat source. Performance evaluation was carried out under various operating conditions, including changes in heat source, absorber, condenser, and evaporator temperatures. Experimental testing was conducted during September 2019. The results indicated that the coefficient of performance (COP) of the absorption cooling system ranged from 0.13 to 0.487, with an evaporator temperature drop of approximately 16 °C. Condensation and absorption temperatures remained below 41 °C, while the maximum driving water temperature reached 80 °C. A steady-state theoretical model was developed using the Engineering Equation Solver (EES) program, applying mass and energy balance equations to predict operating parameters such as temperature, pressure, and COP. Model predictions showed good agreement with the experimental measurements. Furthermore, the results confirmed that generator temperature has a significant influence on overall system performance.
The incorporation of thermal energy storage materials (TESMs) into solar energy systems is a factor that boosts the performance of these systems. In this paper, an experimental study was addressed for enhancing the heat pipe’s thermal performance that works with an Evacuated Solar Tube Collector with Heat Pipe (ETCHP) as a solar water heater system. This is done by adding micro-zinc oxide (ZnO-MP) to the paraffin wax integrated as TESM into the evacuated tube (ET) of the system, where the evaporator section of the heat pipe is completely submerged within the micro-enhanced paraffin wax. Three experimental prototype rigs with one evacuated tube were designed, built, and tested to do the investigation. The most important parameters that have been studied in this study are the thermal resistance and the temperature distribution pattern along the heat pipe. The results show a clear indication of the decrease in the thermal resistance of the heat pipe of the proposed system compared to the system in which pure paraffin wax was incorporated. Also, it was noticed that there is a significant improvement in the temperature distribution along the heat pipe due to the improvement in the conductivity of the micro-enhanced wax compared to the pure wax.
4-Stearoylresorcinol was prepared by acylation of resorcinol with stearoyl chloride in the presence of zinc chloride as catalyst in a batch reactor. The temperature range of reaction was (50-80)°C. The rate of acylation increased with temperature up to (70°C). The conversion of reactants appeared to follow second order kinetic model. The reaction rate constant was (0.0031 1/mol.min) and was higher at higher temperatures. Activation energy was (16.8258 kJ/mol). The optimal catalyst concentration was (2.9936 mol/l). Also, a quantitative relationship was derived to represent the weight of the product as a function to the reaction variables. The quantitative relationship gave mean deviation equal to (5%). The product concentration was measured by UV spectroscopy.