Cover
Vol. 12 No. 2 (2012)

Published: December 31, 2012

Pages: 81-88

Original Article

Synergistic Effect of Some Inorganic Corrosion Inhibitors for Carbon Steel in Cooling Water

Abstract

The current approach to cooling water treatment is to use a multi – component inhibitors. Cooling water formulations containing mixtures of inhibitors usually offer better and increased protection to ferrous metals than similar concentrations of either of the individual components. Such mixtures are synergistic in their action .But; the synergistic effects between nitrites, molybdates and inorganic phosphate were not investigated until recently. A weight loss technique was used to investigate such mixture and to optimize the concentrations of the components in the blend.Consequently; an efficient and effective blend was developed as a corrosion inhibitor for carbon steel in aerated Al–Daura refinery re-circulating cooling water in the pH range 6.75 to 7.25. The preferred concentrations of components in the multi- component inhibitor blend (as ppm ) were: (SN + SM): SHMP = 800: 20 with SN: SM weight ratio =3:2.The reduction in corrosion rate was 97.6 % .

References

  1. Corrosion Inhibitors, Nathan, C.C., NACE, Texas (1973), p.55.
  2. Hennon, K .and Wheeler, D., Power Generation Technologies, Cooling Technology Inst., (2003,), p8.
  3. Gamlen, J., water Treatment During Drought, Garratt-Gallahan CO. Milbrae,CA. (2004), p.10.
  4. Weber, J., Br. Corrosion J., 14, 69, (1979),p. 69.
  5. Corrosion Inhibitors, Rozenfeld, I.L., Mc Graw-Hill, N.Y. (1981), p.220.
  6. Metals Handbook, Corrosion, Boffardi, B.P., vol.13, 9th edition, ASM International, (1987), p.487.
  7. Al-Borno,A.,Islam,M.and Haleem, ,R.,Corrosion,45,990,(1989),p.85.
  8. Al- Borno, A., Islam, M. and khoraishi, R., Corrosion, 45,970(1989),p67.
  9. Sameh, S.A., Ph.D. Thesis, University of Technology (1994), p144.
  10. Tal, M.M., Alwash, S.H. and Hameed, M.S., 2nd .Jordanian Chem.Eng. Confr. , vol1, Irbid, Jordan, Sept., (1996), p.233.
  11. Hasen, E.A., M.Sc. Thesis, University of Technology (1998), p.67.
  12. Ali, A.H., M.Sc. Thesis, University of Technology (2002), p125.
  13. Al-Qasem, M.F., Sayed, S.A. and Tal, M.M., Proceedings, Jordan Intn. Chem. Eng. Confr. , vol.2 (2002),p.34.
  14. Matsuda, S. and Uhlig, H.H., J. Electrochem.Soc., (1964).p.111, 156.
  15. Mercer, A.D., Jenkins, I.D. and Rhodes Brown, J.E., Br. Corrosion J., 3, (1968), p. 136.
  16. Corrosion and Corrosion Control,Uhlig, H.H. and Revie, R.W., 3rd edition, Wiley, N.Y.(1985),p.255.
  17. Cohen, M., Corrosion, (1976).p. 32, 46.
  18. Marshall, A., Corrosion Inhibitors for use in Neutral Water Systems, London, England , Oyez Scientific and Service Ltd.(1983),p11.
  19. Ruijini, G. and Ives, M.B., Corrosion, vol. 45, (1989),p.7.
  20. Tal, M.M., Ph.D. Thesis, University of Technology (1995),p.45.
  21. Corrosion Eng., Fontana, M.G. and Greene, N.D., 2nd .edition, McGraw-Hill, N.Y. (1978), p.66.
  22. Annual Book of ASTM Standard, part10, G31 (1980) p50.
  23. Joseph, C., Proc.3rd.Europ. Symp. Corrosion Inhibitors, University of Ferrara, 1971, p.791.
  24. Corrosion Basics, An introduction,Van Delinder, L.S., NAC (1984),p.234.
  25. Vukasovich, M.S. and Farr, J.P.G., Polyhedron,5,1985, p.11.
  26. Stranick, M.A., Corrosion, 6,40,1984, p. 296