Cover
Vol. 10 No. 2 (2010)

Published: September 30, 2010

Pages: 150-162

Original Article

Alumina-to-Alumina Actively Brazed Using Cu-Ti, Cu-Zr, and Eutectic Ag-Cu-Ti Filler-Metal Alloys

Abstract

Al20rA l10l bronzing systems were produced using a one-stage actively brazed technique based on Cu-Ti, Cu-Zr, and Ag-Cu-Ti alloys. Single and double butt joints were used for micro-structural and mechanical properties studies respectively. The joints that were brazed by using Cu-Zr filler-metal alloys (2%, 4%, 6%, and 8% Zr weight percent) have shown low shear strengths at the 2rO2 interface. Higher shear strength was obtained by using Cu-Ti filler-metal alloys (2%, 4%, 6, and 8% Ti weight percent), and eutectic (Ag-26%C u-4% Ti). As judged by the phases Conned at the interface, Cu2 (AlTi)4O is more effective to wet and both alumina to alumina.

References

  1. H. Pulfrich, "Ceramic to Metal Seals", U.S. Pat. Nos. 2163407 and 2163410, June, 1939.
  2. H.J. Nolte and R.F. Spurch, "Metallizing and Ceramic Sealing with Manganese", U.S. Pat. Nos. 2667432 and 2667427, Jan., 1954.
  3. A.J. Chick and L.J. Speck, "Fabrication of Metal-to-Ceramic Seals", U.S. Pat. No. 2708787, May, 1955.
  4. C.S. Pearsall, "New Brazing Methods for Joining Non-Metallic Material to Metals", Mater. Methods, 30, 61-62 (1942).
  5. F.C. Kelly, "Metallizing and Bonding Non-Metallic Bodies", U.S. Pat. No. 2570248, Oct. 9, 1955.
  6. H. Mizuhara, "Process of Making a Composite Brazing Alloy of Titanium, Copper and Nickel", U.S. Pat. No. 3561099, Feb. 9, 1971.
  7. H. Mizuhara and K. Mally, "Ceramic-to-Metal Joining with Active Brazing Metal", Weld. J., 64 (10) 27-32 (1985).
  8. E. Lugscheider, H. Krappits, and H. Mizuhara, "Joining of Non-Metallized Ceramic with Metals by Insert of Ductile Active Brazing", presented at the Second International Colloquium, Joining of Ceramic, Glass, and Metals, Bad Nauheim, FRG, 1985.
  9. A.J. Moorhead and H. Keating, "Direct Brazing of Ceramics for Advanced Heavy-Duty Diesels", Weld. J., 65 (10) 17-31 (1986).
  10. H. Mizuhara and E. Huebel, "Joining Ceramic to Metal with Ductile Filler Metal", Weld. J., 65 (10) 43-51 (1986).
  11. H. Mizuhara, E. Huebel, and T. Oyama, "High-Reliability Joining of Ceramic to Metal", Ceramic Bulletin, 68 (9) 1591-1599 (1989).